Q

What is a necessary property of the electrolyte used during the refining of metals by electrolysis?

RRB Group D, 10-Feb-26 S-3 2026
✓ Answer: B It must be an aqueous or molten solution of a suitable metal salt
An electrolyte used during the refining of metals by electrolysis must be an aqueous or molten solution of a suitable metal salt. For electrolysis to occur, the electrolyte must contain free-moving ions. In solid form, ions are held in a fixed lattice; therefore, the salt must be dissolved in water or melted to allow these ions to migrate toward the electrodes. In electrolytic refining, the electrolyte is typically a solution of the same metal being refined. This ensures that metal ions can be consistently transferred from the impure anode to the pure cathode. The Cathode Reaction: During the process, metal ions from the electrolyte are reduced (gain electrons) at the negative cathode, where they deposit as pure metal: Cu2+ + 2e- → Cu (pure metal).
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